The effect of mixed alkali on EPR and optical absorption spectra in mixed alkali borate xNa2O–(30−x)K2O–70B2O3 glasses doped with iron ions
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چکیده
منابع مشابه
Optical and Thermal Properties of Mixed Alkali Phosphate Based Glasses
Glassy samples with a composition of 40P2O5–30V2O5–(30-x)Li2O– xK2O, 0<x<30 (mol %) were prepared by the conventional melt quenching technique in two forms of bulk and blown film. X-ray diffraction patterns corroborated the amorphous feature of the samples. Density of samples was investigated by using Archimedes principle. Based on absorption and reflection spectra, indirect a...
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Lead free, eco-friendly bismuth borate glasses doped with alkali oxides of composition xLi2O+(30-x)Na2O+55B2O3+15Bi2O3 (x = 5,10,15,20,25) were prepared by melt quenching technique. Amorphous nature of glasses was confirmed by X-ray diffraction. Density measurements were carried out at room temperature by standard principle of Archimedes with Xylene as an immersion liquid. The non-linear ...
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The “mixed alkali effect” is one of the classical anomalies of glass science. We report here an interesting phenomenon “Mixed Alkali Effect” observed for a series of Cu ions doped xLi2O-(30x)Na2O-70B2O3 (5 ≤ x ≤ 25) glasses, investigated by EPR and optical absorption techniques. The EPR spectra of all the investigated samples exhibit resonance signals characteristic of Cu ions in octahedral sit...
متن کاملModifier Interaction and Mixed-Alkali Effect in Bond Constraint Theory Applied to Ternary Alkali Metaphosphate Glasses
Introducing an interaction parameter γ, we implement modifier interaction and the mixed-alkali effect into bond constraint theory and apply this extension for simplistic property prediction on ternary phosphate glasses. The severity of the mixed-alkali effect results from the interplay of two simultaneous contributions: bond constraints on the modifier species soften and stiffen with decreasing...
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ژورنال
عنوان ژورنال: Journal of Non-Crystalline Solids
سال: 2005
ISSN: 0022-3093
DOI: 10.1016/j.jnoncrysol.2005.03.001